| 1 | David Queiroz & David Preciado |  POR | 30-34 | 55:32 | 29:18 | 22:47 |
| 2 | Vasco Cunha & Amândio Ferreira | POR | 25-29 | 57:01 | 30:30 | 22:56 |
| 3 | Sergio Jiménez Caballero & Manuel Jiménez Caballero |  ESP | 30-34 | 57:20 | 30:14 | 23:36 |
| 4 | Bernardo Branco & Ricardo Fonseca | POR | 25-29 | 58:27 | 30:35 | 24:16 |
| 5 | Sebastian Jonczyk & Joshua Braznell |  GER | 30-34 | 59:41 | 32:09 | 23:45 |
| 6 | Rui Fino & Helder Pinheiro | POR | 45-49 | 59:57 | 31:12 | 24:58 |
| 7 | Osvaldo Lomelí & Joshua Cunha |  MEX | MU29 | 1:00:09 | — | 24:35 |
| 8 | Noelia González Timón & Paula Bernabé | ESP | 25-29 | 1:00:21 | 32:17 | 24:21 |
| 9 | Olivier Fernandez & Jean Patrick Delhaye |  FRA | 45-49 | 1:00:24 | 32:27 | 24:00 |
| 10 | James Hodges & Jamie Mackinnon |  GBR | 30-34 | 1:00:28 | 32:04 | 24:21 |
| 11 | Walter Daniel Arza Zimerman & Adrián Albert Fillol | ESP | 25-29 | 1:01:01 | 33:51 | 23:21 |
| 12 | Will Heylings & Alex Campbell | GBR | 30-34 | 1:01:05 | — | 23:09 |
| 13 | Alberto Vasconcelos & Miguel Carvalho | POR | 30-34 | 1:01:14 | — | 24:23 |
| 14 | Joan Cardona Balaguer & Diego Gabete Rodríguez | ESP | 35-39 | 1:01:32 | 32:24 | 25:18 |
| 15 | Ameriko González Bento & Ismael Gutiérrez Flores | ESP | 30-34 | 1:01:47 | — | 23:44 |
| 16 | Pablo Mardones & Philipp Ringmann |  CHI | 30-34 | 1:02:13 | 33:18 | 24:36 |
| 17 | Marius Brockfeld & Marlon Uwagboe | GER | 30-34 | 1:02:34 | 32:57 | 25:39 |
| 18 | Dominik Clemm & Maximilian Neureuter | GER | 30-34 | 1:02:45 | 33:09 | 25:35 |
| 19 | Mark Whittle & Ian Campbell |  RSA | 40-44 | 1:02:52 | — | 23:57 |
| 20 | Pedro Marques & Ricardo Barros | POR | 30-34 | 1:02:57 | 33:21 | 25:32 |
| 21 | Lauren Scott & Louise White | GBR | 25-29 | 1:02:59 | 33:59 | 25:03 |
| 22 | Vasco Garcez & Francisco Ferrador | POR | MU29 | 1:03:16 | — | 26:23 |
| 23 | Nacho Pedraza & Javier Muñoz | ESP | 40-44 | 1:03:31 | 33:18 | 25:58 |
| 24 | Mitchel Eijgenraam & Jordy Van Hout |  NED | 25-29 | 1:04:04 | 34:23 | 25:19 |
| 25 | Mathieu Bohoteguy & Paul Geny | FRA | 25-29 | 1:04:51 | 34:37 | 26:11 |
| 26 | Hannah Cartwright & Ceri Morgan | GBR | 40-44 | 1:05:21 | 33:34 | 27:51 |
| 27 | David Jose Ortiz Aguado & Leonardo Alonso Mora | ESP | 30-34 | 1:05:36 | — | 24:10 |
| 28 | Josip Pfadt & Thomas Thiel | GER | 30-34 | 1:06:00 | — | 26:14 |
| 29 | Irina Del Río Vallés & Nadine Novillo Rodríguez | ESP | 35-39 | 1:06:26 | 36:07 | 25:53 |
| 30 | Claudia Wilson & Nicola Pearson | GBR | 45-49 | 1:07:05 | 34:56 | 27:47 |
| 31 | Ludovica Midei & Fabrizia Midei |  ITA | WU29 | 1:07:22 | — | 27:30 |
| 32 | Xavier Gesa & Antonio Muñoz | ESP | 35-39 | 1:07:30 | 37:00 | 26:13 |
| 33 | Guillaume Lautrette & Pierre Naura | FRA | 30-34 | 1:07:33 | 34:30 | 28:33 |
| 34 | James Kemsley & Stefan Humphries | GBR | 30-34 | 1:07:52 | — | 28:02 |
| 35 | Kate Collenette & Grace Dovey | GGY | 25-29 | 1:07:55 | 37:04 | 26:27 |
| 36 | Gloria Camilletti & Cecilia Calvigioni | ITA | 30-34 | 1:08:28 | 34:54 | 29:07 |
| 37 | Pedro Afonso & Filipe Belo | POR | 30-34 | 1:08:32 | 37:34 | 26:23 |
| 38 | Christian Caamaño Abelenda & Adrián Pérez García | ESP | 30-34 | 1:08:34 | 37:54 | 26:17 |
| 39 | Michael Boyle & Michael Dennedy |  IRL | 45-49 | 1:08:35 | 34:13 | 29:55 |
| 40 | Fernando Vergillos González & Diego Martínez García | ESP | 30-34 | 1:10:54 | — | 27:54 |
| 41 | Rebecca Carr & Lucy Barker | GBR | 25-29 | 1:11:15 | 38:06 | 28:24 |
| 42 | Hilke Van Der Pols & Anouk Ville | NED | 40-44 | 1:11:28 | 39:53 | 26:54 |
| 43 | Diego De Egea Menéndez & Jaime Castillo Parages | ESP | 30-34 | 1:11:42 | — | 27:45 |
| 44 | Jack Holman & Connor Strudwick | GBR | 30-34 | 1:12:08 | 41:16 | 26:11 |
| 45 | Nicolas Rapeso & Emilio Missale | ESP | 30-34 | 1:12:13 | — | 25:53 |
| 46 | Susana Gameiro & Klara Fialova | POR | 30-34 | 1:12:32 | 39:32 | 28:25 |
| 47 | Ibai Castro Carrera & José Gregorio Núñez Ramírez | ESP | 30-34 | 1:14:16 | 40:46 | 28:43 |
| 48 | Leah Kennedy & Ruth Conlan Trant | IRL | WU29 | 1:14:43 | — | 31:19 |
| 49 | Andrea Potter & Catherine Bradley | GBR | 40-44 | 1:14:44 | — | 31:35 |
| 50 | Lleucu Mains & Elizabeth Harries | GBR | 30-34 | 1:15:25 | 42:36 | 27:42 |
| 51 | Henrike Habuzin & Natalie Otten | GER | 50-54 | 1:15:37 | 38:55 | 31:50 |
| 52 | Ilaria Benedetti & Maria Eleonora Missere | ITA | 25-29 | 1:16:00 | 40:03 | 30:40 |
| 53 | Najwa Maniar & Melanie Gatt | GBR | 45-49 | 1:16:22 | 41:13 | 30:19 |
| 54 | Daphne Glandorf & Pauline Glandorf | NED | 25-29 | 1:16:26 | 41:18 | 29:51 |
| 55 | Vicente Costa Garcia & Pascual Ruiz Verdejo | ESP | 30-34 | 1:17:00 | 40:22 | 31:32 |
| 56 | Niall Clifford & Glenn Smith | IRL | 50-54 | 1:17:15 | — | 32:24 |
| 57 | Ellie Quantrill & Karolina Wachel | GBR | 25-29 | 1:17:23 | 44:59 | 27:33 |
| 58 | Devis Emiliani & Mirko Castelli | ITA | 40-44 | 1:18:20 | 45:09 | 27:35 |
| 59 | Claire Chombeau & Justine Tytgat | FRA | 30-34 | 1:18:30 | 40:00 | 32:12 |
| 60 | Karen Hackney & Svenja Grehn | GBR | 45-49 | 1:18:47 | 47:03 | 26:21 |
| 61 | Ashleigh Kroeger & Holly Mantripp | GBR | 30-34 | 1:19:34 | — | 32:19 |
| 62 | Kathrin Lisken & Caroline Polzin | GER | 35-39 | 1:19:46 | 43:26 | 30:49 |
| 63 | Gill Carey & Annemarie Falk | IRL | 50-54 | 1:21:09 | 44:43 | 31:00 |
| 64 | Selina Wank & Sanne Schop | NED | 30-34 | 1:21:11 | 48:19 | 26:57 |
| 65 | Gina Mcgeever & Maria Jeffery | GBR | 45-49 | 1:23:16 | 40:59 | 37:12 |
| 66 | Phillipa Oreshko & Phoebe Oreshko | GBR | 25-29 | 1:24:04 | 43:03 | 34:59 |
| 67 | Miroslav Brtva & Antonín Mikeska |  CZE | 30-34 | 1:26:51 | — | 29:37 |
| 68 | Helene Joost & Line Gravlund Hansen |  DEN | 35-39 | 1:27:14 | 45:36 | 35:06 |
| 69 | Samantha Ormerod & Katrina Hodges | GBR | 45-49 | 1:32:41 | 48:56 | 37:17 |
| 70 | Gijsje Janssen & Indy Van Loon | NED | 16-24 | 1:37:12 | 48:22 | 41:57 |
| 71 | Rebecca Chilton-Matthews & Laura Mollison |  AUS | 35-39 | 1:39:18 | 59:42 | 28:12 |
| 72 | Alexandra O Brien & Nathalie O Brien | IRL | 25-29 | 1:40:30 | 58:17 | 34:53 |
| 73 | Esmee Den Drijver & Fleur Sinnige | NED | 16-24 | 1:43:29 | 53:25 | 40:44 |
| 74 | Romana Wabera & Martina Janka |  AUT | 40-44 | 1:46:41 | 1:01:08 | 36:49 |