| 1 | Bernardo Branco & Ricardo Fonseca |  POR | 25-29 | 53:08 | 28:37 | 20:57 |
| 2 | Irene Oliván Teixeira & David Oliván Teixeira |  ESP | 25-29 | 54:11 | 29:11 | 21:30 |
| 3 | Stephanie Dollimore & Alex Neville |  GBR | 25-29 | 55:05 | 29:38 | 22:02 |
| 4 | Sven Wierda & Dave Agterhof |  NED | 25-29 | 55:07 | 29:49 | 21:45 |
| 5 | Valentin Galiegue & William Galiegue |  FRA | 25-29 | 55:17 | 28:02 | 22:57 |
| 6 | Jorge Gutiérrez Hellín & Susana Alonso Domínguez | ESP | 30-34 | 55:51 | 29:42 | 22:31 |
| 7 | Jules Penez & Pierre Steenkiste | FRA | 25-29 | 56:02 | 29:00 | 22:56 |
| 8 | Daniel Redondo Muñoz & Ainegue Del Olmo Jimenez | ESP | 30-34 | 56:21 | 29:23 | 23:18 |
| 9 | Jose Restituto & Andrea Serna | ESP | 35-39 | 56:26 | 31:36 | 21:01 |
| 10 | Alexis Charlotteaux & Marjurie Vu | FRA | 25-29 | 57:25 | 31:38 | 21:58 |
| 11 | Maximilian Schröter & Konstantin Jünger |  GER | 35-39 | 57:25 | 30:46 | 22:22 |
| 12 | Roi Barros Corral & David Gómez Fernández | ESP | 35-39 | 57:32 | 30:32 | 23:14 |
| 13 | Diego Lago Ramos & Joaquín Sánchez Arias | ESP | 35-39 | 58:02 | 31:25 | 22:51 |
| 14 | Sara Portela & Fábio Portela | POR | 35-39 | 58:19 | 33:07 | 21:15 |
| 15 | Christophe Carrau & Julien Urrutia | FRA | 30-34 | 59:02 | 32:22 | 22:38 |
| 16 | Carolina Sainz Bautista & Iker De Prado Gonzalez | ESP | 30-34 | 59:06 | 30:25 | 24:52 |
| 17 | PJ Reynolds & Emer Cawley |  IRL | 16-24 | 59:31 | 32:22 | 23:04 |
| 18 | Maxime Louault & Leo Genestre | FRA | 16-24 | 59:40 | 32:15 | 23:15 |
| 19 | Thomas Nortvig & Andreas Vesterholm |  DEN | 35-39 | 59:55 | 33:54 | 21:55 |
| 20 | Toni Chillaron & Cristina Manteiga | ESP | 40-44 | 59:56 | 33:26 | 22:32 |
| 21 | Sean Whelan & Aaron Myles | IRL | 25-29 | 1:00:13 | 31:19 | 24:55 |
| 22 | Antonio Quirós & Iván Quirós | ESP | 40-44 | 1:00:23 | 33:49 | 22:41 |
| 23 | Raúl Refolio Márquez & Marian Donoso Martín | ESP | 40-44 | 1:00:33 | 32:28 | 24:01 |
| 24 | Tomas Vizueta & Carlos Blanes | ESP | 45-49 | 1:01:03 | 31:14 | 25:36 |
| 25 | Jens Nordmeier & Martin Strauch | GER | 45-49 | 1:01:04 | 35:31 | 21:17 |
| 26 | Karolina Wachel & Michael Hamilton | FRA | 30-34 | 1:01:29 | 33:31 | 24:00 |
| 27 | Carlos Ferreira & Isabel Fonseca | POR | 25-29 | 1:01:33 | 32:56 | 24:26 |
| 28 | Josu Martin Rey & Iñaki Nuñez Ayala | ESP | 35-39 | 1:01:35 | 32:15 | 25:27 |
| 29 | Sergio Iglesias Azaña & Alejandro Lacruz Zernov | ESP | 16-24 | 1:02:01 | 35:51 | 21:30 |
| 30 | Jorge Robles Criado & Jesús Álvarez Horrillo | ESP | 45-49 | 1:02:10 | 33:26 | 24:03 |
| 31 | Teo Givaudon & Marien Givaudon | FRA | 25-29 | 1:02:23 | 32:24 | 25:49 |
| 32 | Tom Stables & Mark Jordan | GBR | 30-34 | 1:02:29 | 33:26 | 24:43 |
| 33 | David Sánchez & Quique Parra | ESP | 40-44 | 1:02:31 | 32:48 | 25:34 |
| 34 | Delyth Butler & Hywel Morton | GBR | 45-49 | 1:02:57 | 34:09 | 24:14 |
| 35 | David Alquegui Cano & Guillermo Sainz San Emeterio | ESP | 30-34 | 1:03:13 | 33:39 | 25:16 |
| 36 | Mathias Meunier & Thomas Rochard | FRA | 30-34 | 1:03:31 | 34:49 | 24:05 |
| 37 | Toni Camarasa & Mercedes Ferrando Riera | ESP | 45-49 | 1:03:51 | 35:26 | 24:18 |
| 38 | Jose Miguel Romero Ramos & Sergio Sanchez Alvarez | ESP | 50-54 | 1:04:01 | 33:45 | 25:31 |
| 39 | Sergio Monteagudo & Maite Salgado | ESP | 45-49 | 1:04:06 | 35:02 | 24:42 |
| 40 | Ander Higon & Jon Ander Bueno | ESP | 16-24 | 1:05:12 | 37:42 | 22:52 |
| 41 | Jonny Wells & Niamh Lister | GBR | 30-34 | 1:05:28 | 36:46 | 24:31 |
| 42 | Fiorella Maccio Mangarelli & Sebastián Castagnaro |  URU | 30-34 | 1:05:43 | 37:59 | 22:49 |
| 43 | Carlos Romero Martinez & James Oliver | ESP | 16-24 | 1:05:48 | 36:44 | 24:08 |
| 44 | Iván Varela González & Iván López Gómez | ESP | 35-39 | 1:06:21 | 36:50 | 23:56 |
| 45 | Luis Ribot Fuster & Laura Monedero Garcia | ESP | 25-29 | 1:06:25 | 36:22 | 25:40 |
| 46 | Susanne Kurk & Sara Konert-Uesbeck | GER | 30-34 | 1:06:33 | 38:19 | 23:27 |
| 47 | Alejandro Ocaña Ledesma & María Rocío Pacheco Yepes | ESP | 35-39 | 1:06:38 | 36:58 | 25:25 |
| 48 | Aingeru Gallarreta & Ander Ordorika | ESP | 16-24 | 1:06:56 | 38:34 | 23:45 |
| 49 | Adrian Rouco Lopez & Hugo Mosteiro Mendez | ESP | 35-39 | 1:07:25 | 39:26 | 23:24 |
| 50 | Richard Lawrence & Francesca Stuttard | GBR | 30-34 | 1:07:48 | 37:23 | 25:49 |
| 51 | Mark Westwood & Barrie McGregor | GBR | 60-64 | 1:07:52 | 35:15 | 28:09 |
| 52 | David Calvo Gaite & Claudia Gómez Rodríguez | ESP | 35-39 | 1:07:56 | 35:27 | 27:24 |
| 53 | Manuel Claros & Alberto Giralt | ESP | 35-39 | 1:08:06 | 39:04 | 24:21 |
| 54 | Ana Pacheco & Filipe Neves | POR | 35-39 | 1:08:40 | 39:32 | 24:06 |
| 55 | Anthony Munari & Mickael Munari | FRA | 35-39 | 1:08:43 | 39:44 | 23:13 |
| 56 | David Quirke & Ashling Doherty | IRL | 30-34 | 1:08:47 | 37:17 | 26:52 |
| 57 | Adrià Valero Cabeza & Ángela Pérez Cervera | ESP | 16-24 | 1:08:51 | 36:10 | 28:18 |
| 58 | Viktor Shundik & Nadia Guerra | ESP | 35-39 | 1:08:56 | 38:09 | 25:06 |
| 59 | Alex Burness & Emma Jones | GBR | 30-34 | 1:09:15 | 37:49 | 26:46 |
| 60 | Korey Fogarty & Dylan Fogarty | IRL | 16-24 | 1:09:23 | 38:03 | 26:28 |
| 61 | Júlia Valls Soria & Anna Pla Picazo | ESP | 25-29 | 1:09:23 | 38:18 | 26:36 |
| 62 | Nathan Smith & Joanne Smith | GBR | 40-44 | 1:09:30 | 37:45 | 26:36 |
| 63 | Timme Jongmans & Peter Jongmans | NED | 35-39 | 1:09:37 | 39:01 | 25:54 |
| 64 | Maxime Birabent & Manon Cadio | FRA | 25-29 | 1:09:53 | 36:10 | 28:16 |
| 65 | Norma Sandiumenge Boy & Gala Dolz Feliu | ESP | 25-29 | 1:10:13 | 38:58 | 26:05 |
| 66 | Jero Bonzom Bermejo & Miriam Rodríguez Ibarra | ESP | 35-39 | 1:10:29 | 36:19 | 28:27 |
| 67 | Úria Valle & Ariadna Vial | ESP | 16-24 | 1:10:39 | 37:53 | 27:54 |
| 68 | Júlia Sanfeliu & Àlex Mata | ESP | 25-29 | 1:10:40 | 37:41 | 27:38 |
| 69 | Francesco Borsari & Pierdario Fasciano |  ITA | 35-39 | 1:11:18 | 40:53 | 25:42 |
| 70 | Cristina Martorell Barea & Francesca Arrom Sans | ESP | 25-29 | 1:11:29 | 40:34 | 26:01 |
| 71 | David López Calleja & Veronica Primo Camarero | ESP | 40-44 | 1:11:33 | 38:03 | 27:54 |
| 72 | Carmen Caliz Garcia & José María Vallejo Pendón | ESP | 40-44 | 1:11:48 | 38:31 | 28:16 |
| 73 | Marta Antich Zaragozá & Layla García Lorente | ESP | 25-29 | 1:11:50 | 40:57 | 25:57 |
| 74 | Louis Raymondis & Gabin Alibert | FRA | 16-24 | 1:11:57 | 41:46 | 24:29 |
| 75 | Carina Ananias & Florian Jersch | GER | 35-39 | 1:12:03 | 39:19 | 28:03 |
| 76 | Sonia Merino Requejo & Javier Hernández Bueno | ESP | 50-54 | 1:12:45 | 39:15 | 27:42 |
| 77 | Diego Briseño & Kaila Parcias |  MEX | 16-24 | 1:12:49 | 37:09 | 30:25 |
| 78 | Aitana Ortega & Begoña Egaña | ESP | 25-29 | 1:12:49 | 41:46 | 25:20 |
| 79 | Daniel Nelson & Samantha Harvey | GBR | 25-29 | 1:13:10 | 40:08 | 27:11 |
| 80 | Chloe Oram & John Kavanagh | GBR | 35-39 | 1:13:17 | 42:14 | 25:51 |
| 81 | Berta Carvalho & Anabela Cortez | POR | 40-44 | 1:13:45 | 41:41 | 26:27 |
| 82 | Dafydd Andrews & Emily Saunders | GBR | 25-29 | 1:13:45 | 41:10 | 27:33 |
| 83 | Arianna Lopez & Carmen Lopez | ESP | 16-24 | 1:13:51 | 42:59 | 25:23 |
| 84 | Vânia Cordeiro & António Silva | POR | 40-44 | 1:14:04 | 43:43 | 25:14 |
| 85 | Edgar Gaig & Laura Lozano | ESP | 45-49 | 1:14:19 | 37:37 | 31:01 |
| 86 | Chiara Jaegers & Lars Ulbricht | GER | 30-34 | 1:14:28 | 41:30 | 28:07 |
| 87 | Hannah Heskin & Stephen Heskin | IRL | 40-44 | 1:15:06 | 40:02 | 29:51 |
| 88 | Pablo Bugallo Vilariño & Raquel Esnaloa Bernardo | ESP | 40-44 | 1:15:24 | 41:54 | 27:46 |
| 89 | Lohitzune Andres Letamendia & Pablo Crespo Ferrer | ESP | 35-39 | 1:15:27 | 42:04 | 28:05 |
| 90 | Mónica Espiño Miguez & Verónica Iglesias Permuy | ESP | 35-39 | 1:15:40 | 42:23 | 27:02 |
| 91 | Alaitz Iriarte & Ianire Cortes | ESP | 25-29 | 1:15:48 | 44:01 | 25:47 |
| 92 | Neil Dowling & Brian Kelly | IRL | 35-39 | 1:16:05 | 39:59 | 30:38 |
| 93 | Elena Lopez Uzquiza & Dimas Manuel Robaina Cabrera | ESP | 35-39 | 1:16:29 | 41:38 | 28:36 |
| 94 | Ludovic Caillaud & Theo Modeste | FRA | 25-29 | 1:18:08 | 45:09 | 27:36 |
| 95 | ANTHONY KLEIN & Hermine Brigand | FRA | 35-39 | 1:18:32 | 45:33 | 25:53 |
| 96 | Alaia Urrestarazu & Alba Delgado | ESP | 30-34 | 1:18:49 | 44:20 | 29:02 |
| 97 | Olatz Ruiz & Irati Lasa | ESP | 30-34 | 1:19:08 | 45:07 | 28:29 |
| 98 | Beate Wolf & Bernd Göbel | GER | 60-64 | 1:19:17 | 46:47 | 26:45 |
| 99 | Maria Dolores Tolino Cano & Mari Carmen Martinez Gomariz | ESP | 45-49 | 1:19:57 | 43:23 | 30:26 |
| 100 | Davy Gatebled & Magaly Escartin | FRA | 40-44 | 1:20:39 | 44:51 | 28:56 |
| 101 | Casey Small & Romeo Beckford | GBR | 45-49 | 1:20:40 | 43:44 | 30:17 |
| 102 | Alexandre Saillen & Jesus Daniel Juarez Zaragoza |  SUI | 40-44 | 1:20:58 | 46:26 | 27:18 |
| 103 | Neil Horton & Francisca Marin Martinez | GBR | 45-49 | 1:21:37 | 45:58 | 29:32 |
| 104 | Lisa Stewart & Andreas Grabow | GER | 40-44 | 1:21:57 | 45:53 | 30:23 |
| 105 | Frederic Pagnin & Julien Pagnin | FRA | 40-44 | 1:22:24 | 46:55 | 29:08 |
| 106 | Marian Galmés Cañellas & Mar Parra Mas | ESP | 25-29 | 1:23:04 | 46:42 | 29:03 |
| 107 | Carl Hassan & Iain Woodhams | GBR | 50-54 | 1:23:19 | 44:17 | 33:17 |
| 108 | Sandra Giraud & Lorraine Rees | GBR | 55-59 | 1:24:06 | 44:00 | 33:23 |
| 109 | Anne Solås & Trond Taugbøl |  NOR | 65-69 | 1:25:21 | 44:41 | 32:39 |
| 110 | Hans Kieboom & Patricia Kieboom | NED | 55-59 | 1:25:35 | 45:51 | 31:08 |
| 111 | Kimberley Parisi & Wiltord William | FRA | 30-34 | 1:26:21 | 47:13 | 31:38 |
| 112 | Sonia Colmuto & Stefano Cominetti | ITA | 30-34 | 1:26:22 | 48:52 | 31:47 |
| 113 | John Moran & Emily Conroy | IRL | 30-34 | 1:26:43 | 47:21 | 33:35 |
| 114 | Michelle Mooney & Ann-Marie Moffatt | IRL | 30-34 | 1:27:18 | 52:17 | 28:47 |
| 115 | Paul Cross & Gary Cross | GBR | 45-49 | 1:29:02 | 46:09 | 36:08 |
| 116 | Michelle Cestari & Francesca Conte | ITA | 40-44 | 1:29:04 | 48:57 | 33:49 |
| 117 | Elisa Pohl & Clément Couilleau | FRA | 25-29 | 1:29:06 | 53:56 | 28:23 |
| 118 | Edward Davies & Sara Davies | GBR | 50-54 | 1:30:15 | 49:19 | 33:49 |
| 119 | Nicklas Johansson & Jonas Öhlén |  SWE | 45-49 | 1:31:55 | 52:49 | 32:11 |
| 120 | JUAN ARANA & ALFONSO GEA | ESP | 60-64 | 1:34:17 | 48:21 | 38:43 |
| 121 | David Spells & Julie Spells | GBR | 65-69 | 1:35:05 | 51:14 | 35:23 |
| 122 | Colin Broadbent & Sarah Broadbent | GBR | 50-54 | 1:40:20 | 59:46 | 31:59 |
| 123 | Miquel Parets & Olga Romero | ESP | 40-44 | 1:43:48 | 50:45 | 43:51 |